Thermodynamics of Polymerization. IV. Thermodynamics of Equilibrium Polymerization

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Abstract

Abstract In many cases polymerization proceeds under conditions of equilibrium between polymer and monomer. In some cases an initiator enters into the polymerization equilibria. A general theory of equilibrium polymerization was originally developed by Tobolsky in a long series of papers [1–6]. The particular approach used in the treatment presented here is that developed by Tobolsky and Eisenberg [5].