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A silver - so-called pyrogenic to produce silver nanoparticles by thermal decomposition of the amine complex compound, to provide a process for the preparation of silver nanoparticles is safe and convenient in terms of industrial production that is scaled up . The invention relates to a process for the preparation of silver nano-particles, Aliphatic hydrocarbons amine, a silver compound, were mixed in the presence of an alcohol solvent having 3 or more carbon atoms, to produce a complex compound comprising the silver compound and the amine, The complex compound is heated to by pyrolysis, to form a silver nanoparticle, The method for producing silver nano-particles comprising the. .BACKGROUND