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Mathematics acts an important and essential need in different fields. One of the significant roles in mathematics is played by graph theory that is used in structural models and innovative methods, models in various disciplines for better strategic decisions. In mathematics, graph theory is the study through graphs by which the structural relationship studied with a pair wise relationship between different objects. The different types of network theory or models or model of the network are called graphs. These graphs do not form a part of analytical geometry, but they are called graph theory, which is points connected by lines. The various concepts of graph theory have varied applications in diverse fields. The chapter will deal with graph theory and its application in various financial market decisions. The topological properties of the network of stocks will provide a deeper understanding and a good conclusion to the market structure and connectivity. The chapter is very useful for academicians, market researchers, financial analysts, and economists.