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Stable abnormal N-heterocyclic carbenes and their applications

296 Citations2020
Samaresh Chandra Sau, Pradip Kumar Hota, Swadhin K. Mandal

A review article summarizes the results obtained with the isolated aNHCs, which successfully accomplished the metal-free catalytic formylation of amides using CO2 and the catalytic reduction of carbon dioxide, including atmospheric CO2, into methanol, under ambient conditions.

Abstract

, into methanol, under ambient conditions. Although other transition metal complexes featuring aNHCs as ligand have been prepared and used in catalysis, this review article summarize the results obtained with the isolated aNHCs.