Asymmetric Carboselenenylation Reaction of Alkenes with Aromatic Compounds
Angewandte Chemie International EditionPublished 7 May 2005
Kazuki Okamoto, Yoshiaki Nishibayashi, Sakae Uemura, Akio Toshimitsu
Citations68
SJR quartileQ1
SJR score5.55
SNIP2.47
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Abstract
High diastereoselectivity is attained in the carboselenenylation reaction of simple alkenes with aromatic compounds by using a C2-symmetric areneselenenyl triflate (see scheme). This asymmetric Friedel–Crafts-type reaction is a convenient procedure for the preparation of chiral hydrocarbons bearing an aryl moiety at the stereogenic carbon atom. Tf=trifluoromethanesulfonyl; M.S.=molecular sieves.
Keywords
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