Stereochemistry and mechanism of the asymmetric hydrogenation of unsaturated carboxylic acids catalyzed by binap—-ruthenium(II) dicarboxylate complexes
Tetrahedron LettersPublished 1 January 1990
Tetsuo Ohta, Hidemasa Takaya, Ryōji Noyori
Citations85
SJR quartileQ3
SJR score0.33
SNIP0.43
Generate an AI Snapshot to get a quick, structured summary of this paper.
Study Snapshot
ObjectiveStudy objective
MethodsResearch methodology
PopulationPopulation studied
Sample sizeSample sizes
OutcomesStudy outcomes here
ResultsStudy results comes here
LimitationsResearch study limitations comes here
A concise AI-generated summary of the paper will appear here once you click Generate AI Snapshot.
Abstract
The stereochemical course and pattern of deuterium incorporation of the hydrogenation of unsaturated carboxylic acids catalyzed by Ru(OCOCH3)2(binap) indicate operation of a mechanism involving metal monohydride complexes.
Keywords
ChemistryPharmacology, Toxicology and Pharmaceutics
Journal of the Chemical Society A Inorganic Physical TheoreticalThe preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives
1,421 Citations1966John A. Osborn, F. H. Jardine +2 more
Chemical Society ReviewsCentenary Lecture. Chemical multiplication of chirality: science and applications
408 Citations1989Ryōji Noyori
The Journal of Organic ChemistryAsymmetric hydrogenation of unsaturated carboxylic acids catalyzed by BINAP-ruthenium(II) complexes
343 Citations1987Tetsuo Ohta, Hidemasa Takaya +3 more
ScienceChiral Metal Complexes as Discriminating Molecular Catalysts
270 Citations1990Ryōji Noyori
Chiral metal complexes precisely discriminate between enantiotopic atoms, groups, or faces in achiral molecules and catalyze production of a broad array of natural or unnatural substances of excellent enantiomeric purity.
Inorganic ChemistryBis(diarylphosphino)-1,1 binaphthyl (BINAP)-ruthenium(II) dicarboxylate complexes: new, highly efficient catalysts for asymmetric hydrogenations
213 Citations1988Tetsuo Ohta, Hidemasa Takaya +1 more
NatureHomogeneous Hydrogenation and Hydroformylation using Ruthenium Complexes
205 Citations1965D.J. Evans, John A. Osborn +2 more
Journal of the American Chemical SocietyHomogeneous Catalysis of the Hydrogenation of Olefinic Compounds by Ruthenium(II) Chloride<sup>1</sup>
100 Citations1966Jack Halpern, John F. Harrod +1 more
Pure and Applied ChemistryNew chiral ruthenium complexes for asymmetric catalytic hydrogenations
54 Citations1990Hikaru Takaya, T. OHTA +2 more
Journal of the American Chemical SocietyDihydrogen complexes of metalloporphyrins: characterization and hydrogen-transfer reactivity
53 Citations1990James P. Collman, Paul S. Wagenknecht +2 more
Journal of the American Chemical SocietyPara hydrogen induced polarization in hydrogenation reactions catalyzed by ruthenium phosphine complexes
48 Citations1988Rein U. Kirss, Thomas C. Eisenschmid +1 more
Journal of the Chemical Society Chemical CommunicationsStoicheiometric hydrogenation of olefins using HRuCl(PPh3)3 and formation of an ortho-metallated ruthenium(II) complex
33 Citations1974Brian R. James, Larry D. Markham +1 more
Journal of Molecular CatalysisDihydridotetrakis(triphenylphosphine)ruthenium(II), a catalyst for isomerization, hydrogenation and HD exchange reactions of alkenes
33 Citations1979Sanshiro Komiya, Akio Yamamoto