From Carbon Dioxide to Methane: Homogeneous Reduction of Carbon Dioxide with Hydrosilanes Catalyzed by Zirconium−Borane Complexes
Journal of the American Chemical SocietyPublished 31 August 2006
Tsukasa Matsuo, Hiroyuki Kawaguchi
Citations233
SJR quartileQ1
SJR score5.55
SNIP2.61
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TL;DR
A mixture of a zirconium benzyl phenoxide complex and tris(pentafluorophenyl)borane is reported that catalyzes the hydrosilation reaction of carbon dioxide to generate methane via a bis(silyl)acetal intermediate.
Abstract
A mixture of a zirconium benzyl phenoxide complex and tris(pentafluorophenyl)borane is reported that catalyzes the hydrosilation reaction of carbon dioxide to generate methane via a bis(silyl)acetal intermediate.
Keywords
ChemistryEnergyChemical Engineering
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