Attosecond Control in Photoionization of Hydrogen Molecules

In experiments where hydrogen molecules were dissociatively ionized by an attosecond pulse train in the presence of a near-infrared field, the ionization probability is sensitive to the instantaneous polarization of the molecule by the IR electric field and this work demonstrates that it has probed the IR-induced electron dynamics withAttosecond pulses.

Abstract

We report experiments where hydrogen molecules were dissociatively ionized by an attosecond pulse train in the presence of a near-infrared field. Fragment ion yields from distinguishable ionization channels oscillate with a period that is half the optical cycle of the IR field. For molecules aligned parallel to the laser polarization axis, the oscillations are reproduced in two-electron quantum simulations, and can be explained in terms of an interference between ionization pathways that involve different harmonic orders and a laser-induced coupling between the 1sσ(g) and 2pσ(u) states of the molecular ion. This leads to a situation where the ionization probability is sensitive to the instantaneous polarization of the molecule by the IR electric field and demonstrates that we have probed the IR-induced electron dynamics with attosecond pulses.