Surfaces probed by nonlinear optics
Surface SciencePublished 1 January 1994
Y. R. Shen
Citations343
SJR quartileQ2
SJR score0.42
SNIP0.63
Generate an AI Snapshot to get a quick, structured summary of this paper.
Study Snapshot
ObjectiveStudy objective
MethodsResearch methodology
PopulationPopulation studied
Sample sizeSample sizes
OutcomesStudy outcomes here
ResultsStudy results comes here
LimitationsResearch study limitations comes here
A concise AI-generated summary of the paper will appear here once you click Generate AI Snapshot.
Abstract
Optical second harmonic and sum-frequency generation has recently been proven to be a very versitile probe for surface and interface studies. Here a brief account is given on how the technique was developed and numerous applications found in our laboratory.
Keywords
EngineeringPhysics and Astronomy
Chemical Physics LettersRaman spectra of pyridine adsorbed at a silver electrode
7,053 Citations1974M. Fleischmann, P.J. Hendra +1 more
The Principles of Nonlinear Optics
5,122 Citations1984Y. R. Shen
NatureSurface properties probed by second-harmonic and sum-frequency generation
2,297 Citations1989Y. R. Shen
Physical ReviewLight Waves at the Boundary of Nonlinear Media
1,203 Citations1962N. Bloembergen, P. S. Pershan
Physical ReviewOptical Second-Harmonic Generation in Reflection from Media with Inversion Symmetry
734 Citations1968N. Bloembergen, Richard K. Chang +2 more
Physical Review LettersSum-frequency vibrational spectroscopy of a Langmuir film: Study of molecular orientation of a two-dimensional system
665 Citations1987Philippe Guyot‐Sionnest, James Hunt +1 more
Using infrared-visible sum-frequency generation as a probe, the vibrational spectrum of a monolayer of pentadecanoic acid on a water surface in the CH stretch region is obtained and it was found that the molecules in the liquid condensed phase have their alkane chains extended and oriented nearly normal to the surface, while in theLiquid expanded phase the chains are highly disordered.
Physical review. B, Condensed matterSurface vibrational spectroscopy by infrared-visible sum frequency generation
526 Citations1987Xun Zhu, Hajo Suhr +1 more
The first observation of a vibrational spectrum of a monolayer of molecular adsorbates by infrared-visible sum frequency generation is reported, paving the way for future dynamic studies of surface phonons and molecular vibrations.
Physical Review LettersSurface-Enhanced Second-Harmonic Generation
495 Citations1981C. K. Chen, Alonso Castro +1 more
Progress in Surface ScienceSecond harmonic generation studies of interfacial structure and dynamics
427 Citations1988Geraldine L. Richmond, Jeanne M. Robinson +1 more
Physical Review LettersSecond-Harmonic Reflection from Silicon Surfaces and Its Relation to Structural Symmetry
380 Citations1983H. W. K. Tom, Tony F. Heinz +1 more
Chemical Physics LettersObservation of C-H stretch vibrations of monolayers of molecules optical sum-frequency generation
380 Citations1987James Hunt, Philippe Guyot‐Sionnest +1 more
Physical review. A, General physicsDetermination of molecular orientation of monolayer adsorbates by optical second-harmonic generation
354 Citations1983Tony F. Heinz, H. W. K. Tom +1 more
Modern problems in condensed matter sciencesNonlinear Surface Electromagnetic Phenomena
351 Citations1991
Physical review. B, Solid stateSecond-Harmonic Radiation from Metal Surfaces
350 Citations1971Joseph Rudnick, Edward A. Stern
Physical Review LettersFemtosecond-Time-Resolved Surface Structural Dynamics of Optically Excited Silicon
349 Citations1983C. V. Shank, R. Yen +1 more
Physical review. B, Condensed matterOptical second-harmonic generation from magnetized surfaces
341 Citations1989Ru‐Pin Pan, Hao Wei +1 more
It is shown that surface magnetization can induce a number of nonlinear susceptibility elements that would vanish otherwise and an order-of-magnitude estimate suggests that these induced elements are detectable by optical second-harmonic generation with appropriate polarization combinations.
Physical Review LettersSpectroscopy of Molecular Monolayers by Resonant Second-Harmonic Generation
332 Citations1982Tony F. Heinz, C. K. Chen +2 more
Physical Review LettersStudy of Si(111) Surfaces by Optical Second-Harmonic Generation: Reconstruction and Surface Phase Transformation
271 Citations1985Tony F. Heinz, M. M. T. Loy +1 more
The symmetry properties of the surfaces have been determined by an analysis of polarization dependences of the two reconstructions of the Si(111) 2\ifmmode\times\else\texttimes\fi{}1 and 7\if mmode\ Times\Fi{}7 surfaces.
Physical Review LettersLifetime of an adsorbate-substrate vibration: H on Si(111)
269 Citations1990Philippe Guyot‐Sionnest, P. Dumas +2 more
The measurement of the lifetime of the adsorbate-substrate vibration for hydrogen on silicon by Sum-Frequency Generation shows that the lifetime is 0.8 ns.
Physical Review LettersCoupling of an adsorbate vibration to a substrate surface phonon: H on Si(111)
241 Citations1990P. Dumas, Yves J. Chabal +1 more
High-resolution infrared--reflection-absorption measurements of an unreconstructed, ideally H-terminated Si(111) surface suggest a strong anharmonic coupling between the Si-H stretching and bending modes.
Physical Review LettersEffects of surface magnetism on optical second harmonic generation
227 Citations1991J. Reif, J. C. Zink +2 more
The magneto-optical Kerr erect modifies the hyperpolarizability of the surface in the optical field, leading to a dependence of the second harmonic yield on the direction of magnetization relative to the light fields.
Chemical Physics LettersThe phase of second-harmonic light generated at an interface and its relation to absolute molecular orientation
216 Citations1986Klaus Kemnitz, Kankan Bhattacharyya +4 more
Chemical Physics LettersMonolayer vibrational spectroscopy by infrared-visible sum generation at metal and semiconductor surfaces
202 Citations1987A. L. Harris, Christopher E. D. Chidsey +2 more
Chemical Physics LettersVibrational spectroscopy of a silane monolayer at air/solid and liquid/solid interfaces using sum-frequency generation
188 Citations1988Philippe Guyot‐Sionnest, Richard Superfine +2 more
Physical Review LettersSurface Studies by Optical Second-Harmonic Generation: The Adsorption of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>, CO, and Sodium on the Rh(111) Surface
174 Citations1984H. W. K. Tom, C. Mathew Mate +5 more
Physical Review LettersMolecular vibrational energy relaxation at a metal surface: Methyl thiolate on Ag(111)
172 Citations1990A. L. Harris, Lewis J. Rothberg +3 more
Physical Review LettersDetection of Molecular Monolayers by Optical Second-Harmonic Generation
170 Citations1981C. K. Chen, Tony F. Heinz +2 more
Annual Review of Materials ScienceSurface Second Harmonic Generation: A New Technique for Surface Studies
164 Citations1986Y. R. Shen
Physical Review LettersObservation of molecular reorientation at a two-dimensional-liquid phase transition
153 Citations1985Th. Rasing, Y. R. Shen +2 more
The structure of a monolayer of pentadecanoic acid near the liquid-expanded--liquid-condensed phase transition at a water-air interface is studied by optical second-harmonic generation and shows that the two phases are separated by an inhomogeneous coexistence region on the isotherms.
Physical ReviewMeasurement of the Lowest-Order Nonlinear Susceptibility in III—V Semiconductors by Second-Harmonic Generation with a C<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>Laser
148 Citations1969J. J. Wynne, N. Bloembergen
Physical review. B, Condensed matterVibrational spectra of hydrogen on diamond C(111)-(1×1)
146 Citations1992R. P. Chin, J. Y. Huang +4 more
LangmuirOrientation of molecular monolayers at the liquid-liquid interface as studied by optical second harmonic generation
138 Citations1988S.G. Grubb, Mahn Won Kim +2 more
Physical ReviewTheory of Optical Harmonic Generation at a Metal Surface
135 Citations1965Sudhanshu S. Jha
Chemical Physics LettersSpectroscopic investigations of adsorbates at the metal—electrolyte interface using sum frequency generation
130 Citations1990Philippe Guyot‐Sionnest, A. Tadjeddine
Physical review. B, Condensed matterNonlinear magneto-optical Kerr effect on a nickel surface
117 Citations1989Wolfgang Hübner, K. H. Bennemann
This work calculates the second-order magneto-optical response function in order to determine the nonlinear magneto/optical Kerr effect on the surface of ferromagnetic nickel and calculates nonlinear Kerr spectra which should be observable in surface second-harmonic-generation experiments.
Physical Review LettersTwo-phonon bound state for the hydrogen vibration on the H/Si(111) surface
117 Citations1991Philippe Guyot‐Sionnest
The hot band of the Si-H stretching vibration of the H/Si(111) 1-2-1 surface is investigated using picosecond sum-frequency generation and finds a strong two-phonon bound state.
The Journal of Physical ChemistryPicosecond dynamics of a chemical reaction at the air-water interface studied by surface second harmonic generation
108 Citations1988E. V. Sitzmann, Kenneth B. Eisenthal
Optics LettersOptical second-harmonic generation as a surface probe for noncentrosymmetric media
107 Citations1988T. Stehlin, Marla B. Feller +2 more
It is shown that optical second-harmonic generation can also be used as an effective surface probe with a submonolayer sensitivity for media without inversion symmetry.
The Journal of Chemical PhysicsVibrational energy transfer on hydrogen-terminated vicinal Si(111) surfaces: Interadsorbate energy flow
100 Citations1992M. Morin, P. Jakob +3 more
Surface ScienceStudies of alkali adsorption on Rh(111) using optical second-harmonic generation
97 Citations1986H. W. K. Tom, C. Mathew Mate +4 more
Physical Review LettersSurface Coherent Anti-Stokes Raman Spectroscopy
93 Citations1979C. K. Chen, Alonso Castro +2 more
Journal of Vacuum Science & Technology B Microelectronics Processing and PhenomenaStudy of symmetry and disordering of Si(111)-7×7 surfaces by optical second harmonic generation
89 Citations1985Tony F. Heinz, M. M. T. Loy +1 more
Chemical Physics LettersA novel method for measurements of second-order non-linearities of organic molecules
86 Citations1986Th. Rasing, Garry Berkovic +3 more
Physical review. B, Condensed matterResonant surface second-harmonic generation: Surface states on Ag(110)
82 Citations1992L. E. Urbach, K. L. Percival +3 more
Physical ReviewSecond-Harmonic Generation of Light at the Boundary of an Isotropic Medium
82 Citations1969Charles C. Wang
The Journal of Chemical PhysicsVibrational energy relaxation in a molecular monolayer at a metal surface
81 Citations1989A. L. Harris, N. J. Levinos
Optics LettersContinuous-wave second-harmonic generation as a surface microprobe
75 Citations1986G. T. Boyd, T. W. Hänsch +1 more
It is demonstrated that monolayer detection by optical second-harmonic generation is possible even with a 20-mW cw diode laser, and the same experiments suggest the possibility of an optical monolayers memory device.
Physical Review LettersSecond-Harmonic Generation of Light at the Boundary of Alkali Halides and Glasses
70 Citations1968Charles C. Wang, A. N. Duminski
Physical Review LettersMagnetic-Dipole Contribution to Optical Harmonics in Silver
69 Citations1966Fielding Brown, Robert E. Parks
Physical Review LettersNonlinear Excitation of Surface Polaritons
69 Citations1976F. De Martini, Y. R. Shen
Chemical Physics LettersSurface picosecond raman gain spectra of a molecular monolayer
64 Citations1980J.P. Heritage, David L. Allara
Physical ReviewEffect of Adsorbed Surface Layers on Second-Harmonic Light from Silver
56 Citations1969Fielding Brown, Masahiro Matsuoka
Surface ScienceRole of surface electronic transitions in linear and nonlinear electromagnetic phenomena at noble metal surfaces: beyond jellium
55 Citations1991Meiqi Jiang, Gary Alan Pajer +1 more
Optics LettersCoherent second-harmonic generation by counterpropagating surface plasmons
51 Citations1979C. K. Chen, Alonso Castro +1 more
This work has observed second-harmonic generation by counterpropagating surface-plasmon waves by well-collimated beam along the surface normal in excellent agreement with theoretical prediction.
Optics CommunicationsOptical second-harmonic generation from submonolayer Na-covered Ge surfaces
50 Citations1973J.M. Chen, John R. Bower +2 more
Journal of the Optical Society of AmericaExperimental Study of Optical Second-Harmonic Generation in Silver*
43 Citations1968H. Sonnenberg, Hubert C. Heffner
The Journal of Physical ChemistrySecond harmonic generation from Langmuir-Blodgett films of retinal and retinal Schiff bases
40 Citations1988Jung Y. Huang, Aaron Lewis +1 more
The Journal of Chemical PhysicsStudy of monolayer polymerization using nonlinear optics
39 Citations1986Garry Berkovic, Th. Rasing +1 more
Optics LettersObservation of coherent Raman scattering in thin-film optical waveguides
37 Citations1984W. M. Hetherington, G. I. Stegeman +3 more
This work has measured coherent surface Raman scattering in 2-microm-thick films of polystyrene by guiding the incident and scattered light in the film, in excellent agreement with theoretical predictions.
The Journal of Chemical PhysicsThe observation of rotational anisotropy in the second harmonic intensity from a Ag(111) electrode
32 Citations1987V. L. Shannon, Daniel A. Koos +1 more
Physical review. B, Condensed matter<i>In situ</i>determination of the structure of an electrodeposited monolayer using optical second-harmonic generation
30 Citations1988J. Miragliotta, T. E. Furtak
Physical Review LettersPolarization of Free Potassium Atoms by Exchange Collisions with Sodium Atoms and Free Electrons
26 Citations1958Peter Franken, Richard H. Sands +1 more
Physical review. A, General physics<i>In situ</i>determination of induced dipole moments of pure and membrane-bound retinal chromophores
26 Citations1989Th. Rasing, J. Huang +3 more
The orientation, spectrum, and the change in dipole moment upon optical excitation for monolayers of retinal chromophores, which are of relevance for visual excitation are obtained by using the technique of optical second-harmonic generation.
Applied OpticsSecond harmonic generation for in situ analysis of electrode surface structure
25 Citations1987V. L. Shannon, Daniel A. Koos +1 more
The nonlinear optical technique of second harmonic generation has been used as an in situ probe of surface structure and symmetry at the electrode-electrolyte interface to demonstrate that an ordered surface is present.
Journal of Physics Condensed MatterOptical second-harmonic generation for studying surfaces and interfaces
25 Citations1989J. F. McGilp
TrAC Trends in Analytical ChemistrySurface studies with optical second-harmonic generation
24 Citations1989Tony F. Heinz, Georg A. Reider
Electrochimica ActaTime resolved second harmonic generation studies of double layer reorganization: sulfate adsorption and desorption on a polycrystalline silver electrode
15 Citations1989Jeanne M. Robinson, Geraldine L. Richmond
The Journal of Chemical PhysicsEthylene adsorption on ZnO: CARS spectroscopy with optical waveguides
15 Citations1987W. M. K. P. Wijekoon, Z. Z. Ho +1 more
Chinese Journal of PhysicsOptical Second Harmonic Generation as a Probe for Surface Magnetization
9 Citations1987Ru‐Pin Pan, Y. R. Shen
Japanese Journal of Applied PhysicsOptical Second Harmonic Generation from Surfaces
8 Citations1974J. M. Chen, J. R. Bowert +1 more
…
