Instability of the eye in the dark and proprioception
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TL;DR
It is reported here that, in the absence of visual and vestibular stimuli, the eye ipsilateral to the section becomes unstable and performs slow pendular oscillations.
Abstract
<p>First report on the sequential, visible light-initiated, single unit monomer insertion (SUMI) of N,N-dimethylacrylamide (DMAm) into the reversible addition fragmentation chain transfer (RAFT) agent, 4-((((2-carboxyethyl)thio)carbonothioyl)thio)-4-cyanopentanoic acid (CTA<sub>1</sub>), in aqueous solution is provided. The specificity for SUMI over formation of higher oligomers and/or RAFT agent-derived by-products is higher for longer irradiation wavelengths. Red light provides the cleanest product (selective SUMI), showing a linear pseudo-first order kinetic profile to high (&gt;80%) conversion, but also the slowest reaction rate. Blue light provides a relatively rapid reaction, but also gives some by-products (&lt;2%) and the kinetic profile displays a conversion plateau at &gt;65% conversion. Higher specificity with red light is attributed to CTA<sub>1</sub> absorbing at longer wavelengths than the SUMI product, which allows selective excitation of CTA<sub>1</sub>. The use of a higher reaction temperature (65 °C vs ambient) results in a higher reaction rate and a reduction in oligomer formation.</p>
