Constituents of the venom of a south african fire ant (solenopsis punctaticeps)
TetrahedronPublished 1 January 1976
D. J. PEDDER, Henry M. Fales, T. Jaouni, Murray S. Blum, John G. MacConnell, Robin M. Crewe
Citations80
SJR quartileQ3
SJR score0.43
SNIP0.60
Generate an AI Snapshot to get a quick, structured summary of this paper.
Study Snapshot
ObjectiveStudy objective
MethodsResearch methodology
PopulationPopulation studied
Sample sizeSample sizes
OutcomesStudy outcomes here
ResultsStudy results comes here
LimitationsResearch study limitations comes here
A concise AI-generated summary of the paper will appear here once you click Generate AI Snapshot.
TL;DR
Structures of a series of 2,5-dialkylpyrrolidines and -pyrrolines isolated from the South African fire ant are determined by gas chromatography-mass spectrometry and confirmed by synthesis using the Hofmann-Loffler reaction on the corresponding primary amine.
Abstract
Structures of a series of 2,5-dialkylpyrrolidines and -pyrrolines isolated from the South African fire ant, Solenopsis punctaticeps, are determined by gas chromatography-mass spectrometry and confirmed by synthesis using the Hofmann-Löffler reaction on the corresponding primary amine.
Keywords
Agricultural and Biological SciencesNeuroscienceBiochemistry, Genetics and Molecular Biology
TetrahedronThe chemistry of fire ant venom
164 Citations1971John G. MacConnell, Murray S. Blum +1 more
ToxiconFire ant venoms: Comparative analyses of alkaloidal components
164 Citations1972J. M. Brand, Murray S. Blum +2 more
The alkaloids of the red and black forms mainly contain an alkenyl group in position 6 and a trans configuration of the substituents on the piperidine ring, while those of the two indigenous species of North American fire ants contain alkyl substituent which are both cis and trans on the ring.
Australian Journal of ZoologyA generic revision of the world Myrmicinae related to Solenopsis and Pheidologeton (Hymenoptera : Formicidae)
117 Citations1966G. Ettershank
New, as well as old disused, taxonomic characters are examined, especially meristic ones, and these are applies to a critical analysis of tribes Solenopsidini and Pheidologetini of authors, and the old conventional tribal groupings prove to have little utility.
Archives of DermatologySkin Responses to the Sting of the Imported Fire Ant (Solenopsis Saevissima)
89 Citations1957Robert Marcus
The fire ant causes destruction to crops and, according to Travis, 2 as many as 15% of the native fire ants of the South are destructive.
Journal of the American Chemical SocietyTHE SYNTHESIS OF DIHYDROCONESSINE. A METHOD FOR FUNCTIONALIZING STEROIDS AT C<sub>18</sub>
71 Citations1958E. J. Corey, W. R. Hertler
ScienceIsolation of a Hemolytic Component of Fire Ant Venom
66 Citations1959George A. Adrouny, Vincent J. Derbes +1 more
A crystalline hemolytic principle, shown to be a constituent of fire ant venom and having the properties of an amine, was isolated from crude extracts of whole ants.
Insect BiochemistryBiochemical evolution in fire ant venoms
62 Citations1973J. M. Brand, Murray S. Blum +1 more
The distribution of 2,6-dialkyl(and alkenyl-)piperidine alkaloids in the venom of fire ant workers of Solenopsis xyloni, S. geminata, and S. richteri has been compared with the occurrence of these compounds in the Venom of alate queens of the same species, leading to the proposal that the venoms of S. invicta are more highly evolved.
Journal of the American Chemical SocietyThe Synthesis of Dihydroconessine<sup>1</sup>
44 Citations1959E. J. Corey, W. R. Hertler
Journal of the American Chemical SocietyThe Structure of Alkyl-Substituted Pyrrolines<sup>1</sup>
38 Citations1951Gordon G. Evans
Annals of the Entomological Society of AmericaNew Alkaloids in the Venoms of Fire Ants
33 Citations1974John G. MacConnell, Roger N. Williams +2 more
2 piperidine alkaloids of lower molecular weight are reported as the sole components in the venom of a Solenopsis population (new species to be described elsewhere) from Brazil, and as minor constituents in those of alate females of both S. geminata and S. richteri from the United States.
Accounts of Chemical ResearchBiosynthesis of the hemlock and related piperidine alkaloids
25 Citations1971Edward Leete
Annals of the Entomological Society of AmericaChemistry of the Venom of Solenopsis aurea (Hymenoptera: Formicidae)
22 Citations1973Murray S. Blum, J. M. Brand +2 more
The venom of the fire ant, Solenopsis invicta Buren, consists primarily of the trans -isomers of a series of dialkylpiperidines which may be partly responsible for the toxic properties of this secretion.
Journal of the American Chemical SocietyStudies on the Cyclization of N-Chlorodialkylamines
16 Citations1960S. Wawzonek, Townley P. Culbertson
Chemische BerichteHofmann‐Löffler‐Reaktion mit primären Aminen
14 Citations1966Ernst Schmitz, Detlef Murawski
ScienceFire Ant Venom: Synthesis of a Reported Component of Solenamine
7 Citations1967Philip E. Sonnet
2-Methyl-3-hexadecylpyrrolidine was synthesized and has hemolytic activity as has solenamine, but it apparently does not have the insecticidal activity of the fire ant venom.
